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Issue 1, 2008
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Steric control of the nuclearity of metallamacrocycles: formation of a hexanuclear gallium metalladiazamacrocycle and a hexadecanuclear manganese metalladiazamacrocycle

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Abstract

An S6-symmetric hexanuclear gallium metalladiazamacrocycle, [GaIII6L26S6] with a –(ΛΔ)(ΛΔ)– chiral sequence and an S8-symmetric hexadecanuclear manganese metalladiazamacrocycle, [MnIII16L216S16] with a –(ΛΛΔΔ)(ΛΛΔΔ)– chiral sequence were prepared using the same N2-trans-cinnamoyl-2-hydroxy-3-naphthoylhydrazide (H3L2) as a bridging pentadentate ligand between the metal centers for the formation of a macrocyclic system.

Graphical abstract: Steric control of the nuclearity of metallamacrocycles: formation of a hexanuclear gallium metalladiazamacrocycle and a hexadecanuclear manganese metalladiazamacrocycle

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Publication details

The article was received on 31 Jul 2007, accepted on 30 Oct 2007 and first published on 16 Nov 2007


Article type: Paper
DOI: 10.1039/B711686A
Citation: Dalton Trans., 2008,0, 131-136
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    Steric control of the nuclearity of metallamacrocycles: formation of a hexanuclear gallium metalladiazamacrocycle and a hexadecanuclear manganese metalladiazamacrocycle

    K. Lee, R. P. John, M. Park, D. Moon, H. Ri, G. H. Kim and M. S. Lah, Dalton Trans., 2008, 0, 131
    DOI: 10.1039/B711686A

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