Issue 40, 2008
From the journal:

Physical Chemistry Chemical Physics

First observation of the elusive iodocarbene: ground state multiplicity and singlet–triplet gap of CHI†

Chong Tao,a   Carlena Ebben,a   Hsiang-Ting Koa  and  Scott A. Reid*a  

* Corresponding authors

a Department of Chemistry, Marquette University, Milwaukee, US
E-mail: scott.reid@mu.edu
Fax: +1 (0)414 288 7066
Tel: +1 (0)414 288 7565

Abstract

We report the first observation of iodocarbene (CHI) using fluorescence excitation and emission spectroscopy, which indicate a singlet ground state and a lower bound to the singlet–triplet gap of 3.76 kcal mol−1.

Graphical abstract: First observation of the elusive iodocarbene: ground state multiplicity and singlet–triplet gap of CHI

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Article information

DOI
https://doi.org/10.1039/B812734D
Article type
Communication
Submitted
24 Jul 2008
Accepted
07 Aug 2008
First published
03 Sep 2008

Phys. Chem. Chem. Phys., 2008,10, 6090-6092

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First observation of the elusive iodocarbene: ground state multiplicity and singlet–triplet gap of CHI

C. Tao, C. Ebben, H. Ko and S. A. Reid, Phys. Chem. Chem. Phys., 2008, 10, 6090 DOI: 10.1039/B812734D

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