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Issue 3, 2008
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Variation of polarizability in the [4n + 2] annulene series: from [22]- to [66]-annulene

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Abstract

Using correlated ab initio methods, the polarizability of large [4n + 2]-annulenes is determined, showing that there exists an almost linear relation between the exaltation of magnetic susceptibility (a measure of aromaticity) and an equivalent enlargement of polarizability.

Graphical abstract: Variation of polarizability in the [4n + 2] annulene series: from [22]- to [66]-annulene

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Article information


Submitted
03 Sep 2007
Accepted
18 Oct 2007
First published
07 Nov 2007

Phys. Chem. Chem. Phys., 2008,10, 361-365
Article type
Paper

Variation of polarizability in the [4n + 2] annulene series: from [22]- to [66]-annulene

I. García Cuesta, J. Sánchez Marín, T. Bondo Pedersen, H. Koch and A. M. J. Sánchez de Merás, Phys. Chem. Chem. Phys., 2008, 10, 361
DOI: 10.1039/B713459B

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