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Issue 12, 2008
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Solid state synthesis of coordination compounds from basic metal salts

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Abstract

The preparation of the complex salts [H2im]2[MCl4] (H2im = imidazolium, M = Co, 1; Zn, 2; Cu, 3) and coordination compounds [MCl2(Him)2] (M = Co, 4; Zn, 5; Cu, 6) by a range of solid-state and solid-gas reactions is reported. Compounds 4–6 and the related [{MCl2(4,4′-bipy)}n] (M = Co, 7; Zn, 8) were prepared by the solid state reactions of metal hydroxide or carbonate salts (or their equivalent) with the hydrochloride salt of the appropriate ligand (imidazole or 4,4′-bipy).

Graphical abstract: Solid state synthesis of coordination compounds from basic metal salts

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Article information


Submitted
12 Jun 2008
Accepted
29 Jul 2008
First published
03 Sep 2008

CrystEngComm, 2008,10, 1790-1795
Article type
Paper

Solid state synthesis of coordination compounds from basic metal salts

C. J. Adams, M. A. Kurawa, M. Lusi and A. G. Orpen, CrystEngComm, 2008, 10, 1790
DOI: 10.1039/B809950B

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