Issue 8, 2008
From the journal:

CrystEngComm

Nanosized lanthanide oxide rods in I1O3 hybrid organic–inorganic frameworks involving in situligand synthesis†

Lan-Fen Chen,a   Jian Zhang,a   Guo-Qiang Ren,a   Zhao-Ji Li,a   Ye-Yan Qin,a   Pei-Xiu Yin,a   Jian-Kai Chenga  and  Yuan-Gen Yao*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian, China
E-mail: yyg@fjirsm.ac.cn

Abstract

Presented here are three interesting I1O3 lanthanide-transition metal coordination polymers [Ln2Cu(μ6–O)1/6(μ3–OH)2/3(μ3–OH)2(hpzc)2(H2O)2]·2H2O [Ln = Dy(1), Ho(2), Er(3); Hhpzc = 3-hydroxy-pyrazine-2-carboxylic acid], based on nano-sized Ln-O-Ln inorganic rods and in situ obtained 3-hydroxy-pyrazine-2-carboxylate which came from pyrazine-2,3-dicarboxylic acid (H2pzdc). It is the first time that nanorods are incorporated into metal–organic frameworks.

Graphical abstract: Nanosized lanthanide oxide rods in I1O3 hybrid organic–inorganic frameworks involving in situ ligand synthesis

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Article information

DOI
https://doi.org/10.1039/B804490B
Article type
Paper
Submitted
17 Mar 2008
Accepted
02 May 2008
First published
29 May 2008

CrystEngComm, 2008,10, 1088-1092

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Nanosized lanthanide oxide rods in I1O3 hybrid organic–inorganic frameworks involving in situ ligand synthesis

L. Chen, J. Zhang, G. Ren, Zhao-Ji Li, Y. Qin, P. Yin, J. Cheng and Y. Yao, CrystEngComm, 2008, 10, 1088 DOI: 10.1039/B804490B

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