Issue 8, 2008
From the journal:

CrystEngComm

The crystallisation and packing of [Cr(C2O4Ag(PPh3)2)3] (Ph3P/Ph3PO) (MeNO2)4†

Philip A. W. Dean,*a   Donald C. Craig,b   Marcia L. Scudderb  and  Ian G. Dance*b  

* Corresponding authors

a Department of Chemistry, University of Western Ontario, London, Ontario, Canada

b School of Chemistry, University of New South Wales, Sydney, NSW, Australia

Abstract

We describe the syntheses of Ag3(PPh3)9[Cr(ox)3] and Ag3(PPh3)6[Cr(ox)3] (ox2− = oxalate dianion) and the crystal structure of [Cr(C2O4Ag(PPh3)2)3]·(Ph3P)0.73·(Ph3PO)0.27·(MeNO2)4 obtained when Ag3(PPh3)9[Cr(ox)3] is crystallised from nitromethane/CH2Cl2. This crystal is ineffectively packed and does not utilise the intermolecular multiple phenyl embraces present in the crystal structures of related compounds.

Graphical abstract: The crystallisation and packing of [Cr(C2O4Ag(PPh3)2)3] (Ph3P/Ph3PO) (MeNO2)4

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Article information

DOI
https://doi.org/10.1039/B803643H
Article type
Paper
Submitted
03 Mar 2008
Accepted
16 Apr 2008
First published
09 May 2008

CrystEngComm, 2008,10, 1044-1046

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The crystallisation and packing of [Cr(C2O4Ag(PPh3)2)3] (Ph3P/Ph3PO) (MeNO2)4

P. A. W. Dean, D. C. Craig, M. L. Scudder and I. G. Dance, CrystEngComm, 2008, 10, 1044 DOI: 10.1039/B803643H

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