Issue 3, 2008
From the journal:

CrystEngComm

Inclusion of pyridine and acetone by a diol host: structure, thermal stability and kinetics of desolvation†

Ayesha Jacobs,*a   Nana L. Z. Masuku,a   Luigi R. Nassimbenia  and  Jana H. Taljaardb  

* Corresponding authors

a Department of Chemistry, Faculty of Applied Sciences, Cape Peninsula University of Technology, PO Boz 652, Cape Town, South Africa
E-mail: jacobsa@cput.ac.za
Fax: 27 21 4603854
Tel: 27 21 4603167

b Department of Chemistry, Nelson Mandela Metropolitan University, Port Elizabeth, South Africa

Abstract

The host compound, 1,4-di-(5H-dibenzo[a,d]cyclohepten-5-ol)-buta-1,3-diyne, H, forms inclusion compounds with pyridine(H·2PYR) and acetone(H·2ACE). Their crystal structures, thermal behaviour and kinetics of desolvation have been determined. In addition the effect of particle size on the onset of guest release has also been studied.

Graphical abstract: Inclusion of pyridine and acetone by a diol host: structure, thermal stability and kinetics of desolvation

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Article information

DOI
https://doi.org/10.1039/B713769A
Article type
Paper
Submitted
07 Sep 2007
Accepted
24 Oct 2007
First published
02 Nov 2007

CrystEngComm, 2008,10, 322-326

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Inclusion of pyridine and acetone by a diol host: structure, thermal stability and kinetics of desolvation

A. Jacobs, N. L. Z. Masuku, L. R. Nassimbeni and J. H. Taljaard, CrystEngComm, 2008, 10, 322 DOI: 10.1039/B713769A

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