Issue 1, 2008
From the journal:

CrystEngComm

Formation of a sandwich-type supercomplex through second-sphere coordination of functionalized macrocyclic polyamines†

Xiandong Zhu,a   Zhen Ma,a   Wenhua Bi,a   Yuling Wang,a   Daqiang Yuana  and  Rong Cao*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fujian, Fuzhou, P.R. China
E-mail: rcao@ fjirsm.ac.cn
Fax: +86-591-83796710
Tel: +86-591-83796710

Abstract

A novel sandwich-type supercomplex, namely {[Er(TETA)]2Er(H2O)8}NO3·10H2O (1), has been self-assembled through the conjoined hydrogen bonds by using a tetraaza-functionalized macrocyclic polyamine ligand, showing complete incorporation of the octahydrate lanthanide cation between the second coordination spheres.

Graphical abstract: Formation of a sandwich-type supercomplex through second-sphere coordination of functionalized macrocyclic polyamines

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Article information

DOI
https://doi.org/10.1039/B710633E
Article type
Communication
Submitted
12 Jul 2007
Accepted
12 Sep 2007
First published
26 Sep 2007

CrystEngComm, 2008,10, 19-22

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Formation of a sandwich-type supercomplex through second-sphere coordination of functionalized macrocyclic polyamines

X. Zhu, Z. Ma, W. Bi, Y. Wang, D. Yuan and R. Cao, CrystEngComm, 2008, 10, 19 DOI: 10.1039/B710633E

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