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Issue 42, 2008
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Rotational spectrum and equilibrium structure of silanethione, H2Si[double bond, length as m-dash]S

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Abstract

Unsubstituted silanethione, H2Si[double bond, length as m-dash]S, has been characterized experimentally for the first time by means of rotational spectroscopy; the equilibrium structure of this fundamental molecule has been evaluated through a combination of experimental data from a total of ten isotopologues and results of high-level coupled-cluster calculations.

Graphical abstract: Rotational spectrum and equilibrium structure of silanethione, H2Si [[double bond, length as m-dash]] S

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Publication details

The article was received on 20 Aug 2008, accepted on 23 Sep 2008 and first published on 01 Oct 2008


Article type: Communication
DOI: 10.1039/B814558J
Citation: Chem. Commun., 2008,0, 5292-5294
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    Rotational spectrum and equilibrium structure of silanethione, H2Si[double bond, length as m-dash]S

    S. Thorwirth, J. Gauss, M. C. McCarthy, F. Shindo and P. Thaddeus, Chem. Commun., 2008, 0, 5292
    DOI: 10.1039/B814558J

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