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Issue 43, 2008
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Design of chiral bifunctional secondary amine catalysts for asymmetric enamine catalysis

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Abstract

A series of binaphthyl-based secondary amine catalysts containing various functional groups have been designed as new chiral bifunctional amine catalysts. These chiral organocatalysts have been successfully applied to several asymmetric reactions viaenamine intermediates and exhibit unique reactivity and selectivity in comparison with proline and its derivatives.

Graphical abstract: Design of chiral bifunctional secondary amine catalysts for asymmetric enamine catalysis

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Publication details

The article was received on 02 Jun 2008, accepted on 16 Jul 2008 and first published on 10 Sep 2008


Article type: Feature Article
DOI: 10.1039/B809301F
Citation: Chem. Commun., 2008,0, 5465-5473

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    Design of chiral bifunctional secondary amine catalysts for asymmetric enamine catalysis

    T. Kano and K. Maruoka, Chem. Commun., 2008, 0, 5465
    DOI: 10.1039/B809301F

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