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Issue 43, 2008
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1-Azadienes in cycloaddition and multicomponent reactions towards N-heterocycles

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Abstract

1-Azadienes are versatile building blocks for the efficient construction of various N-heterocycles. Depending on the substitution pattern and reaction partner, they may participate in a range of different reactions. An overview of recent methods for the generation of 1-azadienes is presented, as well as their application in cycloaddition, electrocyclization, and multicomponent reactions. Considering the broad range of reactivities and resulting heterocyclic scaffold structures, 1-azadienes are very useful reactive intermediates for the development of modular reaction sequences in diversity-oriented synthesis.

Graphical abstract: 1-Azadienes in cycloaddition and multicomponent reactions towards N-heterocycles

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Publication details

The article was received on 30 May 2008, accepted on 16 Jul 2008 and first published on 08 Sep 2008


Article type: Feature Article
DOI: 10.1039/B809206K
Citation: Chem. Commun., 2008,0, 5474-5489

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    1-Azadienes in cycloaddition and multicomponent reactions towards N-heterocycles

    B. Groenendaal, E. Ruijter and R. V. A. Orru, Chem. Commun., 2008, 0, 5474
    DOI: 10.1039/B809206K

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