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Issue 34, 2008
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Remote induction of asymmetry in [13]-macro-dilactone topology by a single stereogenic center

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Abstract

Analysis of a series of unsaturated [13]-macro-dilactones showed that the configuration of a single carbon dictates the planar chirality of a macrocycle backbone and in turn remotely switches the facial display of an embedded alkene unit.

Graphical abstract: Remote induction of asymmetry in [13]-macro-dilactone topology by a single stereogenic center

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Supplementary files

Article information


Submitted
06 May 2008
Accepted
17 Jun 2008
First published
29 Jul 2008

Chem. Commun., 2008, 4028-4030
Article type
Communication

Remote induction of asymmetry in [13]-macro-dilactone topology by a single stereogenic center

W. S. Fyvie and M. W. Peczuh, Chem. Commun., 2008, 4028
DOI: 10.1039/B807562J

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