Issue 34, 2008
From the journal:

Chemical Communications

Remote induction of asymmetry in [13]-macro-dilactone topology by a single stereogenic center†

W. Sean Fyviea  and  Mark W. Peczuh*a  

* Corresponding authors

a Department of Chemistry, University of Connecticut, Storrs, USA
E-mail: mark.peczuh@uconn.edu
Fax: +1-860-486-2981
Tel: +1-860-486-1605

Abstract

Analysis of a series of unsaturated [13]-macro-dilactones showed that the configuration of a single carbon dictates the planar chirality of a macrocycle backbone and in turn remotely switches the facial display of an embedded alkene unit.

Graphical abstract: Remote induction of asymmetry in [13]-macro-dilactone topology by a single stereogenic center

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Article information

DOI
https://doi.org/10.1039/B807562J
Article type
Communication
Submitted
06 May 2008
Accepted
17 Jun 2008
First published
29 Jul 2008

Chem. Commun., 2008, 4028-4030

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Remote induction of asymmetry in [13]-macro-dilactone topology by a single stereogenic center

W. S. Fyvie and M. W. Peczuh, Chem. Commun., 2008, 4028 DOI: 10.1039/B807562J

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