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Issue 34, 2008
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Remote induction of asymmetry in [13]-macro-dilactone topology by a single stereogenic center

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Abstract

Analysis of a series of unsaturated [13]-macro-dilactones showed that the configuration of a single carbon dictates the planar chirality of a macrocycle backbone and in turn remotely switches the facial display of an embedded alkene unit.

Graphical abstract: Remote induction of asymmetry in [13]-macro-dilactone topology by a single stereogenic center

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Publication details

The article was received on 06 May 2008, accepted on 17 Jun 2008 and first published on 29 Jul 2008


Article type: Communication
DOI: 10.1039/B807562J
Citation: Chem. Commun., 2008,0, 4028-4030

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    Remote induction of asymmetry in [13]-macro-dilactone topology by a single stereogenic center

    W. S. Fyvie and M. W. Peczuh, Chem. Commun., 2008, 0, 4028
    DOI: 10.1039/B807562J

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