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Issue 26, 2008
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Controlling the formation of 1 out of 64 stereoisomers using organocatalysis

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Abstract

The formation of 1 out of 64 stereoisomers, i.e. controlling the creation of 6 stereocenters, of important optically active bicyclo[3.3.1]non-2-ene compounds, has been achieved using organocatalysis; the reaction proceeds with excellent stereocontrol and can be carried out with the generation of enantiopure products using chromatography-free procedures.

Graphical abstract: Controlling the formation of 1 out of 64 stereoisomers using organocatalysis

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Publication details

The article was received on 15 Apr 2008, accepted on 12 May 2008 and first published on 09 Jun 2008


Article type: Communication
DOI: 10.1039/B806418K
Citation: Chem. Commun., 2008,0, 3016-3018

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    Controlling the formation of 1 out of 64 stereoisomers using organocatalysis

    S. Bertelsen, R. L. Johansen and K. A. Jørgensen, Chem. Commun., 2008, 0, 3016
    DOI: 10.1039/B806418K

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