Jump to main content
Jump to site search

Issue 40, 2008
Previous Article Next Article

Synthesis and reactivity of bis(imido) uranium(vi) cyclopentadienyl complexes

Author affiliations

Abstract

The bis(imido) uranium(VI)–C5H5 and –C5Me5 complexes (C5H5)2U(NtBu)2, (C5Me5)2U(NtBu)2, (C5H5)U(NtBu)2(I)(dmpe), and (C5H5)2U(NtBu)2(dmpe) can be synthesized from reactions between U(NtBu)2(I)2(L)x (L = THF, x = 2; L = dmpe, x = 1) and Na(C5R5) (R = H, Me); these complexes represent the first structurally characterized C5H5-compounds of uranium(VI) and they further highlight the differences between UO22+ and the bis(imido) fragment.

Graphical abstract: Synthesis and reactivity of bis(imido) uranium(vi) cyclopentadienyl complexes

Back to tab navigation

Supplementary files

Article information


Submitted
11 Apr 2008
Accepted
19 Jul 2008
First published
09 Sep 2008

Chem. Commun., 2008, 4986-4988
Article type
Communication

Synthesis and reactivity of bis(imido) uranium(VI) cyclopentadienyl complexes

L. P. Spencer, R. L. Gdula, T. W. Hayton, B. L. Scott and J. M. Boncella, Chem. Commun., 2008, 4986
DOI: 10.1039/B806075D

Social activity

Search articles by author

Spotlight

Advertisements