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Issue 27, 2008
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A three-dimensional lanthanide-organic radical open-framework

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Abstract

The reaction of a 3-connecting PTMTC radical with Tb(III) ions forms a three-dimensional open-framework with the formula [Tb(PTMTC)(DMF)3] (1), which associates a lattice complex T topology with large channels, guest-induced reversible crystal to amorphous transformations and ferromagnetic metal-radical interactions.

Graphical abstract: A three-dimensional lanthanide-organic radical open-framework

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Article information


Submitted
07 Feb 2008
Accepted
09 Apr 2008
First published
08 May 2008

Chem. Commun., 2008, 3160-3162
Article type
Communication

A three-dimensional lanthanide-organic radical open-framework

N. Roques, D. Maspoch, I. Imaz, A. Datcu, J. Sutter, C. Rovira and J. Veciana, Chem. Commun., 2008, 3160
DOI: 10.1039/B802196A

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