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Issue 27, 2008
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A three-dimensional lanthanide-organic radical open-framework

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The reaction of a 3-connecting PTMTC radical with Tb(III) ions forms a three-dimensional open-framework with the formula [Tb(PTMTC)(DMF)3] (1), which associates a lattice complex T topology with large channels, guest-induced reversible crystal to amorphous transformations and ferromagnetic metal-radical interactions.

Graphical abstract: A three-dimensional lanthanide-organic radical open-framework

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Publication details

The article was received on 07 Feb 2008, accepted on 09 Apr 2008 and first published on 08 May 2008

Article type: Communication
DOI: 10.1039/B802196A
Citation: Chem. Commun., 2008,0, 3160-3162

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    A three-dimensional lanthanide-organic radical open-framework

    N. Roques, D. Maspoch, I. Imaz, A. Datcu, J. Sutter, C. Rovira and J. Veciana, Chem. Commun., 2008, 0, 3160
    DOI: 10.1039/B802196A

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