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Issue 25, 2008
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Synthesis of N,N-disubstituted phosphoramidatesvia a Lewis acid-catalyzed phosphorimidate rearrangement

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Abstract

A Lewis acid-catalyzed rearrangement of phosphorimidates allows a direct, high-yielding transformation of azides with commercially available phosphites into secondary phosphoramidates.

Graphical abstract: Synthesis of N,N-disubstituted phosphoramidatesvia a Lewis acid-catalyzed phosphorimidate rearrangement

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Publication details

The article was received on 05 Feb 2008, accepted on 27 Mar 2008 and first published on 18 Apr 2008


Article type: Communication
DOI: 10.1039/B802030B
Citation: Chem. Commun., 2008,0, 2932-2934

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    Synthesis of N,N-disubstituted phosphoramidatesvia a Lewis acid-catalyzed phosphorimidate rearrangement

    I. Wilkening, G. del Signore and C. P. R. Hackenberger, Chem. Commun., 2008, 0, 2932
    DOI: 10.1039/B802030B

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