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Issue 17, 2008
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An atom-efficient conjugation approach to well-defined block copolymers using RAFT chemistry and hetero Diels–Alder cycloaddition

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Abstract

The tendency of electron-deficient dithioesters to undergo hetero Diels–Alder cycloadditions is successfully used to generate polymer conjugates between a RAFT-polymerized poly(styrene) and a diene-terminated poly(ε-caprolactone).

Graphical abstract: An atom-efficient conjugation approach to well-defined block copolymers using RAFT chemistry and hetero Diels–Alder cycloaddition

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Article information


Submitted
26 Nov 2007
Accepted
28 Jan 2008
First published
20 Feb 2008

Chem. Commun., 2008, 2052-2054
Article type
Communication

An atom-efficient conjugation approach to well-defined block copolymers using RAFT chemistry and hetero Diels–Alder cycloaddition

S. Sinnwell, A. J. Inglis, T. P. Davis, M. H. Stenzel and C. Barner-Kowollik, Chem. Commun., 2008, 2052
DOI: 10.1039/B718180A

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