Issue 1, 2008

1,2-Addition of trialkylaluminium reagents to N-diphenylphosphinoylketimines in the absence of any additional reagents

Abstract

Using reactive trialkylaluminium reagents for the 1,2-addition on acetophenone- and benzophenone-derived ketimines, α-trisubstituted amines were obtained in excellent yields up to 99%.

Graphical abstract: 1,2-Addition of trialkylaluminium reagents to N-diphenylphosphinoylketimines in the absence of any additional reagents

Supplementary files

Article information

Article type
Communication
Submitted
13 Sep 2007
Accepted
11 Oct 2007
First published
23 Oct 2007

Chem. Commun., 2008, 105-107

1,2-Addition of trialkylaluminium reagents to N-diphenylphosphinoylketimines in the absence of any additional reagents

R. Reingruber and S. Bräse, Chem. Commun., 2008, 105 DOI: 10.1039/B714161K

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