Issue 45, 2008
From the journal:

Chemical Communications

Modular chiral dendritic monodentate phosphoramidite ligands for Rh(ii)-catalyzed asymmetric hydrogenation: unprecedented enhancement of enantioselectivity†

Feng Zhang,ab   Yong Li,a   Zhi-Wei Li,a   Yan-Mei He,a   Shou-Fei Zhu,c   Qing-Hua Fan*a  and  Qi-Lin Zhou*c  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, Center for Chemical Biology, Institute of Chemistry, Chinese Academy of Sciences, Beijing, P. R. China

b Graduate School of the Chinese Academy of Sciences, Beijing, P. R. China

c State Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin, P. R. China
E-mail: fanqh@iccas.ac.cn, qlzhou@nankai.edu.cn

Abstract

Modular chiral dendrimers with monodentate phosphoramidite ligands located at the core were synthesized and applied in the Rh-catalyzed asymmetric hydrogenations, afforded unprecedented enhancement of enantioselectivity.

Graphical abstract: Modular chiral dendritic monodentate phosphoramidite ligands for Rh(ii)-catalyzed asymmetric hydrogenation: unprecedented enhancement of enantioselectivity

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Article information

DOI
https://doi.org/10.1039/B815380A
Article type
Communication
Submitted
03 Sep 2008
Accepted
30 Sep 2008
First published
15 Oct 2008

Chem. Commun., 2008, 6048-6050

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Modular chiral dendritic monodentate phosphoramidite ligands for Rh(II)-catalyzed asymmetric hydrogenation: unprecedented enhancement of enantioselectivity

F. Zhang, Y. Li, Z. Li, Y. He, S. Zhu, Q. Fan and Q. Zhou, Chem. Commun., 2008, 6048 DOI: 10.1039/B815380A

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