Issue 44, 2008
From the journal:

Chemical Communications

Hexacyanoosmate(iii) chemistry: preparation and magnetic properties of a pentanuclear cluster and a Prussian blue analogue with Ni(ii)†

Matthew G. Hilfiger,a   Michael Shatruk,b   Andrey Prosvirina  and  Kim R. Dunbar*a  

* Corresponding authors

a Dept. of Chemistry Texas A&M University, College Station, TX, USA
E-mail: dunbar@mail.chem.tamu.edu
Fax: 1-979-845-7177
Tel: 1-979-845-5235

b Dept. of Chemistry and Biochemistry Florida State University, Tallahassee, USA
E-mail: shatruk@chem.fsu.edu

Abstract

The hexacyanoosmate(III) anion was used to prepare a pentanuclear cyanide bridged molecular cluster with ligand-protected Ni(II) ions as well as the corresponding Prussian blue phase from a reaction with aqueous Ni(II) ions.

Graphical abstract: Hexacyanoosmate(iii) chemistry: preparation and magnetic properties of a pentanuclear cluster and a Prussian blue analogue with Ni(ii)

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Article information

DOI
https://doi.org/10.1039/B813413H
Article type
Communication
Submitted
05 Aug 2008
Accepted
26 Sep 2008
First published
15 Oct 2008

Chem. Commun., 2008, 5752-5754

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Hexacyanoosmate(III) chemistry: preparation and magnetic properties of a pentanuclear cluster and a Prussian blue analogue with Ni(II)

M. G. Hilfiger, M. Shatruk, A. Prosvirin and K. R. Dunbar, Chem. Commun., 2008, 5752 DOI: 10.1039/B813413H

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