Issue 47, 2008
From the journal:

Chemical Communications

A snapshot of a coordination polymerself-assembly process: the crystallization of a metastable 3D network followed by the spontaneous transformation in water to a 2D pseudopolymorphic phase†

Thierry Bataille,a   Ferdinando Costantino,*b   Andrea Ienco,*c   Annalisa Guerri,d   Fabio Marmottinib  and  Stefano Midollinic  

* Corresponding authors

a Science Chimique de Rennes (UMR-CNRS 6226), Université de Rennes 1, Avenue du General Leclerc, Rennes Cedex, France

b Dipartimento di Chimica e CEMIN, Università di Perugia, Via Elce di Sotto, 8, Perugia, Italy
E-mail: fcost@unipg.it
Fax: ++39 075 5855566
Tel: ++39 075 5855563

c ICCOM-CNR, Via Madonna del Piano, 10, Sesto fiorentino Florence, Italy
E-mail: andrea.ienco@iccom.cnr.it
Fax: ++39 055 5225203
Tel: ++39 055 5225282

d Dipartimento di Chimica, Università di Firenze, Via della Lastruccia, Sesto fiorentino (Florence), Italy

Abstract

A metastable copper(II) 3D hybrid with 4,4′-bipyridine (4,4′-bipy) and P,P′-diphenylethylenediphosphinate (pc2p2–) undergoes a spontaneous, quantitative, transformation to a stable 2D polymorphic species either spontaneously in water, or after thermal dehydration followed by hydration.

Graphical abstract: A snapshot of a coordination polymer self-assembly process: the crystallization of a metastable 3D network followed by the spontaneous transformation in water to a 2D pseudopolymorphic phase

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Article information

DOI
https://doi.org/10.1039/B813222D
Article type
Communication
Submitted
05 Aug 2008
Accepted
07 Oct 2008
First published
04 Nov 2008

Chem. Commun., 2008, 6381-6383

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A snapshot of a coordination polymer self-assembly process: the crystallization of a metastable 3D network followed by the spontaneous transformation in water to a 2D pseudopolymorphic phase

T. Bataille, F. Costantino, A. Ienco, A. Guerri, F. Marmottini and S. Midollini, Chem. Commun., 2008, 6381 DOI: 10.1039/B813222D

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