Issue 44, 2008
From the journal:

Chemical Communications

Mononuclear Ti[triple bond, length as m-dash]N complexes formed by the facile multiple deprotonation of H3N·B(C6F5)3: the importance of chloride ligands†

Anna-Marie Fuller,a   William Clegg,b   Ross W. Harrington,b   David L. Hughesa  and  Simon J. Lancaster*a  

* Corresponding authors

a Wolfson Materials and Catalysis Centre, School of Chemical Sciences and Pharmacy, University of East Anglia, Norwich, UK
E-mail: S.Lancaster@uea.ac.uk
Fax: +44 1603 592003
Tel: +44 1603 592009

b School of Chemistry, Newcastle University, Newcastle upon Tyne, UK

Abstract

The crystalline ion-pair [TiCl(NMe2)2(NMe2H)2]+[TiCl2{NB(C6F5)3}(NMe2H)2]−, in which the anion has a triply bonded nitridoborate ligand, is formed through the multiple activation of H3N·B(C6F5)3 when treated with [Ti(NMe2)3Cl].

Graphical abstract: Mononuclear Ti [[triple bond, length as m-dash]] N complexes formed by the facile multiple deprotonation of H3N·B(C6F5)3: the importance of chloride ligands

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Article information

DOI
https://doi.org/10.1039/B812785A
Article type
Communication
Submitted
25 Jul 2008
Accepted
15 Sep 2008
First published
08 Oct 2008

Chem. Commun., 2008, 5776-5778

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Mononuclear Ti[triple bond, length as m-dash]N complexes formed by the facile multiple deprotonation of H3N·B(C6F5)3: the importance of chloride ligands

A. Fuller, W. Clegg, R. W. Harrington, D. L. Hughes and S. J. Lancaster, Chem. Commun., 2008, 5776 DOI: 10.1039/B812785A

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