Issue 44, 2008
From the journal:

Chemical Communications

A proton–hydride diiron complex with a base-containing diphosphine ligand relevant to the [FeFe]-hydrogenase active site†

Ning Wang,a   Mei Wang,*a   Tingting Zhang,a   Ping Li,a   Jihong Liua  and  Licheng Sun*ab  

* Corresponding authors

a State Key Laboratory of Fine Chemicals, DUT-KTH Joint Education and Research Centre on Molecular Devices, Dalian University of Technology (DUT), Dalian, China
E-mail: symbueno@dlut.edu.cn
Fax: +86 411 83702185
Tel: +86 411 88993886

b Department of Chemistry, Royal Institute of Technology (KTH), Stockholm, Sweden

Abstract

A diiron dithiolate complex holding a μ-hydride on the iron atoms and a proton on the basic site of a chelating diphosphine ligand was prepared and crystallographically characterized as a structural model of the [FeFe]-hydrogenase active site, and its molecular structure shows the Hμ−⋯HN+ distance is 3.934 Å.

Graphical abstract: A proton–hydride diiron complex with a base-containing diphosphine ligand relevant to the [FeFe]-hydrogenase active site

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Article information

DOI
https://doi.org/10.1039/B811352A
Article type
Communication
Submitted
03 Jul 2008
Accepted
20 Aug 2008
First published
01 Oct 2008

Chem. Commun., 2008, 5800-5802

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A proton–hydride diiron complex with a base-containing diphosphine ligand relevant to the [FeFe]-hydrogenase active site

N. Wang, M. Wang, T. Zhang, P. Li, J. Liu and L. Sun, Chem. Commun., 2008, 5800 DOI: 10.1039/B811352A

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