Issue 39, 2008
From the journal:

Chemical Communications

Temperature-triggered gate opening for gas adsorption in microporous manganese formate†

Hyunuk Kim,a   Denis G. Samsonenko,‡a   Minyoung Yoon,a   Ji Woong Yoon,b   Young Kyu Hwang,b   Jong-San Chang*b  and  Kimoon Kim*a  

* Corresponding authors

a National Creative Research Initiative Center for Smart Supramolecules (CSS) and Department of Chemistry, Pohang University of Science and Technology (POSTECH), Pohang, Korea
E-mail: kkim@postech.ac.kr
Fax: +82 54-279-8129
Tel: +82 54-279-2113

b Catalysis Center for Molecular Engineering, Korea Research Institute of Chemical Technology (KRICT), PO Box 107, Yusung, Daejeon, Korea
E-mail: jschang@krict.re.kr
Fax: +82 42-860-7676
Tel: +82 42-860-7673

Abstract

Microporous manganese formate shows temperature-triggered gate opening for nitrogen and argon adsorption, which is not due to a structural change of the framework but due to dynamic opening of the pore aperture and/or sufficient kinetic energy of the adsorbates to overcome a diffusion barrier above a critical temperature.

Graphical abstract: Temperature-triggered gate opening for gas adsorption in microporous manganese formate

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Article information

DOI
https://doi.org/10.1039/B811087E
Article type
Communication
Submitted
30 Jun 2008
Accepted
04 Aug 2008
First published
26 Aug 2008

Chem. Commun., 2008, 4697-4699

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Temperature-triggered gate opening for gas adsorption in microporous manganese formate

H. Kim, D. G. Samsonenko, M. Yoon, J. W. Yoon, Y. K. Hwang, J. Chang and K. Kim, Chem. Commun., 2008, 4697 DOI: 10.1039/B811087E

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