Issue 38, 2008
From the journal:

Chemical Communications

Spontaneous formation of a chiral supramolecular superhelix in the crystalline state using a single-stranded tetranuclear metallohelicate†

Shigehisa Akine,a   Takashi Matsumotoa  and  Tatsuya Nabeshima*a  

* Corresponding authors

a Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Japan
E-mail: nabesima@chem.tsukuba.ac.jp
Fax: +81-29-853-4507
Tel: +81-29-853-4507

Abstract

An unprecedented one-handed coiled-coil structure was formed in the crystal of a Zn3La tetranuclear metallohelicate, in which the handedness of both the helical component and the helical array was well controlled by the chiral auxiliary of the flexible acyclic ligand.

Graphical abstract: Spontaneous formation of a chiral supramolecular superhelix in the crystalline state using a single-stranded tetranuclear metallohelicate

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Article information

DOI
https://doi.org/10.1039/B810426C
Article type
Communication
Submitted
19 Jun 2008
Accepted
24 Jul 2008
First published
27 Aug 2008

Chem. Commun., 2008, 4604-4606

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Spontaneous formation of a chiral supramolecular superhelix in the crystalline state using a single-stranded tetranuclear metallohelicate

S. Akine, T. Matsumoto and T. Nabeshima, Chem. Commun., 2008, 4604 DOI: 10.1039/B810426C

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