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Abstract | Cited by

Two remote dialkylaluminium centres supported by a macrocyclic Schiff base ligand exhibited beneficial cooperative effects, whilst aluminoxane-type bonding proved to be detrimental to activity for the ring opening polymerisation of ε-caprolactone.

Graphical abstract: Multinuclear alkylaluminium macrocyclic Schiff base complexes: influence of procatalyst structure on the ring opening polymerisation of ε-caprolactone

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