Issue 42, 2008
From the journal:

Chemical Communications

Encapsulated molecular catalysts in polysiloxane gels: ruthenium cluster-catalyzed isomerization of alkenes†

Yukihiro Motoyama,ab   Motonori Abe,b   Kazuyuki Kamo,b   Yusuke Kosakoa  and  Hideo Nagashima*ab  

* Corresponding authors

a Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga, Japan
E-mail: nagasima@cm.kyushu-u.ac.jp
Fax: +81-92-583-7819
Tel: +81-92-583-7819

b Graduate School of Engineering Sciences, Kyushu University, Kasuga, Japan

Abstract

Novel ruthenium-encapsulating polysiloxane gels are prepared by treatment of polymethylhydrosiloxane with diols in the presence of (μ3,η2,η3,η5-acenaphthylene)Ru3(CO)7, and act as reusable catalysts in the isomerization of alkenes without leakage of the catalyst species.

Graphical abstract: Encapsulated molecular catalysts in polysiloxane gels: ruthenium cluster-catalyzed isomerization of alkenes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B809937E
Article type
Communication
Submitted
11 Jun 2008
Accepted
11 Jul 2008
First published
17 Sep 2008

Chem. Commun., 2008, 5321-5323

Permissions

Request permissions

Encapsulated molecular catalysts in polysiloxane gels: ruthenium cluster-catalyzed isomerization of alkenes

Y. Motoyama, M. Abe, K. Kamo, Y. Kosako and H. Nagashima, Chem. Commun., 2008, 5321 DOI: 10.1039/B809937E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements