Issue 41, 2008
From the journal:

Chemical Communications

Two-dimensional ordering of benzenethiol self-assembled monolayers guided by displacement of cyclohexanethiols on Au(111)†

Hungu Kang,a   Haiwon Lee,a   Youngjong Kang,a   Masahiko Harabc  and  Jaegeun Noh*a  

* Corresponding authors

a Department of Chemistry, Hanyang University, 17 Haengdang-dong, Seongdong-gu, Korea
E-mail: jgnoh@hanyang.ac.kr
Fax: +82 2 2299 0762
Tel: +82 2 22200938

b Flucto-order Functions Asian Collaboration Team, RIKEN, 2-1 Hirosawa, Wako, Japan

c Department of Electronic Chemistry, Tokyo Institute of Technology, 4259 Nagatsuta, Midoriku, Japan

Abstract

Although the adsorption of benzenethiols (BT) on Au(111) usually leads to the formation of disordered phases, we demonstrate here that the displacement of preadsorbed cyclohexanethiol self-assembled monolayers (SAMs) on Au(111) by BT molecules can be a successful approach to obtain two-dimensional BT SAMs with long-range ordered domains.

Graphical abstract: Two-dimensional ordering of benzenethiol self-assembled monolayers guided by displacement of cyclohexanethiols on Au(111)

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Article information

DOI
https://doi.org/10.1039/B809261C
Article type
Communication
Submitted
02 Jun 2008
Accepted
18 Jul 2008
First published
12 Sep 2008

Chem. Commun., 2008, 5197-5199

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Two-dimensional ordering of benzenethiol self-assembled monolayers guided by displacement of cyclohexanethiols on Au(111)

H. Kang, H. Lee, Y. Kang, M. Hara and J. Noh, Chem. Commun., 2008, 5197 DOI: 10.1039/B809261C

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