Issue 38, 2008
From the journal:

Chemical Communications

Surface binding vs. sequestration; the uptake of benzohydroxamic acid at iron(iii) oxide surfaces†

Iria M. Rio-Echevarria,a   Fraser J. White,a   Euan K. Brechin,a   Peter A. Tasker*a  and  Steven G. Harris*b  

* Corresponding authors

a University of Edinburgh, School of Chemistry, West Mains Road, Edinburgh, UK
E-mail: peter.tasker@ed.ac.uk
Fax: (+44) 131 650 6453
Tel: (+44) 131 650 4706

b Infineum UK Ltd, PO Box 1, Milton Hill, Abingdon, Oxon, UK
E-mail: steve.harris@infineum.com
Fax: (+44) 1235 46 9371
Tel: (+44) 1235 46 9368

Abstract

Benzohydroxamic acid is shown to be an unexpectedly good ligand for iron(III) oxides, favouring surface attachment to the formation of trisbenzohydroxamato complexes, which are known to have very high thermodynamic stability in solution.

Graphical abstract: Surface binding vs. sequestration; the uptake of benzohydroxamic acid at iron(iii) oxide surfaces

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Article information

DOI
https://doi.org/10.1039/B808805E
Article type
Communication
Submitted
27 May 2008
Accepted
10 Jul 2008
First published
06 Aug 2008

Chem. Commun., 2008, 4570-4572

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Surface binding vs. sequestration; the uptake of benzohydroxamic acid at iron(III) oxide surfaces

I. M. Rio-Echevarria, F. J. White, E. K. Brechin, P. A. Tasker and S. G. Harris, Chem. Commun., 2008, 4570 DOI: 10.1039/B808805E

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