Issue 35, 2008
From the journal:

Chemical Communications

Methylidynearsine (HC[triple bond, length as m-dash]As): synthesis and direct characterization by UV-photoelectron spectroscopy and mass spectrometry†‡

Jean-Claude Guillemin,*a   Anna Chrostowska,*b   Alain Dargelos,b   Thi Xuan Mai Nguyen,b   Alain Graciaac  and  Pierre Guenotd  

* Corresponding authors

a Sciences Chimiques de Rennes, Ecole Nationale Supérieure de Chimie de Rennes-CNRS, Rennes, France
E-mail: jean-claude.guillemin@ensc-rennes.fr
Tel: 33 22323 8073

b Institut Pluridisciplinaire de Recherche sur l’Environnement et les Matériaux, Université de Pau et des Pays de l’Adour – CNRS – Av. de l’Université, BP 1155, Pau, France
E-mail: anna.chrostowska@univ-pau.fr
Tel: 33 55940 7580

c Laboratoire des Fluides Complexes, Université de Pau et des Pays de l’Adour – CNRS. Av. de l’Université, BP 1155, Pau, France

d Centre Régional de Mesures Physiques de l’Ouest, Université de Rennes 1, Rennes, France

Abstract

The dehydrohalogenation of gaseous dichloromethylarsine on solid base led to chloromethylidenearsine and, at higher temperature of the base, to methylidynearsine, the third unsubstituted heteroalkyne unambiguously synthesized up to now.

Graphical abstract: Methylidynearsine (HC [[triple bond, length as m-dash]] As): synthesis and direct characterization by UV-photoelectron spectroscopy and mass spectrometry

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Article information

DOI
https://doi.org/10.1039/B806771F
Article type
Communication
Submitted
22 Apr 2008
Accepted
27 May 2008
First published
10 Jul 2008

Chem. Commun., 2008, 4204-4206

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Methylidynearsine (HC[triple bond, length as m-dash]As): synthesis and direct characterization by UV-photoelectron spectroscopy and mass spectrometry

J. Guillemin, A. Chrostowska, A. Dargelos, T. X. M. Nguyen, A. Graciaa and P. Guenot, Chem. Commun., 2008, 4204 DOI: 10.1039/B806771F

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