Issue 29, 2008
From the journal:

Chemical Communications

Tracking reactive intermediates in phosphine-promoted reactions with ambiphilic phosphino-boranes†‡

Sylvie Moebs-Sanchez,a   Ghenwa Bouhadir,a   Nathalie Saffon,b   Laurent Maron*c  and  Didier Bourissou*a  

* Corresponding authors

a Université Paul Sabatier, Laboratoire Hétérochimie Fondamentale et Appliquée du CNRS (UMR 5069), Equipe « Ligands Bifonctionnels et Polymères Biodégradables », 118 route de Narbonne, France
E-mail: dbouriss@chimie.ups-tlse.fr
Fax: +33 (0)5 6155 8204
Tel: +33 (0)5 6155 7737

b Université Paul Sabatier, Structure Fédérative Toulousaine en Chimie Moléculaire (FR 2599), 118 route de Narbonne, France

c Université Paul Sabatier, INSA, Laboratoire de Physique et Chimie des Nanoobjets (UMR 5215), 135 avenue de Rangueil, France

Abstract

The ambiphilic phosphino-borane i-Pr2P(o-C6H4)BMes2 affords stable versions of key zwitterionic intermediates by reactions with diethyl azodicarboxylate or PhNCO.

Graphical abstract: Tracking reactive intermediates in phosphine-promoted reactions with ambiphilic phosphino-boranes

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Article information

DOI
https://doi.org/10.1039/B805161E
Article type
Communication
Submitted
27 Mar 2008
Accepted
22 Apr 2008
First published
28 May 2008

Chem. Commun., 2008, 3435-3437

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Tracking reactive intermediates in phosphine-promoted reactions with ambiphilic phosphino-boranes

S. Moebs-Sanchez, G. Bouhadir, N. Saffon, L. Maron and D. Bourissou, Chem. Commun., 2008, 3435 DOI: 10.1039/B805161E

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