Issue 25, 2008
From the journal:

Chemical Communications

Rh(ii)-catalyzed skeletal reorganization of enynes involving selective cleavage of C–C triple bonds†

Kazusa Otaa  and  Naoto Chatani*a  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan
E-mail: chatani@chem.eng.osaka-u.ac.jp
Fax: +81 6 6879 7396
Tel: +81 6 6879 7397

Abstract

Treatment of enynes with a catalytic amount of Rh(II) complex results in skeletal reorganization to give cis-configured 1-vinylcycloalkenes, the formation of which occurs via double cleavage of both C–C double and C–C triple bonds.

Graphical abstract: Rh(ii)-catalyzed skeletal reorganization of enynes involving selective cleavage of C–C triple bonds

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Article information

DOI
https://doi.org/10.1039/B805100C
Article type
Communication
Submitted
26 Mar 2008
Accepted
21 Apr 2008
First published
29 May 2008

Chem. Commun., 2008, 2906-2907

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Rh(II)-catalyzed skeletal reorganization of enynes involving selective cleavage of C–C triple bonds

K. Ota and N. Chatani, Chem. Commun., 2008, 2906 DOI: 10.1039/B805100C

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