Issue 27, 2008
From the journal:

Chemical Communications

Concerted attack of frustrated Lewis acid–base pairs on olefinic double bonds: a theoretical study†

András Stirling,a   Andrea Hamza,a   Tibor András Rokoba  and  Imre Pápai*a  

* Corresponding authors

a Chemical Research Center of HAS, Pusztaszeri út 59-67, H-1025 Budapest, Hungary
E-mail: papai@chemres.hu
Fax: +3613257554
Tel: +3614381121

Abstract

A computational approach reveals cooperative action of the preorganized acidic and basic centers of the frustrated P(t-Bu)3/B(C6F5)3 Lewis pair on olefinic bonds as the key to the observed regioselective addition reaction.

Graphical abstract: Concerted attack of frustrated Lewis acid–base pairs on olefinic double bonds: a theoretical study

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Article information

DOI
https://doi.org/10.1039/B804662J
Article type
Communication
Submitted
18 Mar 2008
Accepted
07 Apr 2008
First published
09 May 2008

Chem. Commun., 2008, 3148-3150

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Concerted attack of frustrated Lewis acid–base pairs on olefinic double bonds: a theoretical study

A. Stirling, A. Hamza, T. A. Rokob and I. Pápai, Chem. Commun., 2008, 3148 DOI: 10.1039/B804662J

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