Issue 29, 2008
From the journal:

Chemical Communications

Rhodium-catalyzed (E)-selective cross-dimerization of terminal alkynes†

Takashi Katagiri,a   Hayato Tsurugi,a   Tetsuya Satoha  and  Masahiro Miura*a  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Japan
E-mail: miura@chem.eng.osaka-u.ac.jp

Abstract

Cross-dimerization of various terminal alkynes with different bulky terminal alkynes such as triisopropylsilylacetylene and 1-trimethylsilyloxy-1,1-diphenyl-2-propyne efficiently proceeds in the presence of a rhodium catalyst system to produce the corresponding (E)-enynes with high regio- and stereoselectivity.

Graphical abstract: Rhodium-catalyzed (E)-selective cross-dimerization of terminal alkynes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B804573A
Article type
Communication
Submitted
17 Mar 2008
Accepted
08 Apr 2008
First published
07 May 2008

Chem. Commun., 2008, 3405-3407

Permissions

Request permissions

Rhodium-catalyzed (E)-selective cross-dimerization of terminal alkynes

T. Katagiri, H. Tsurugi, T. Satoh and M. Miura, Chem. Commun., 2008, 3405 DOI: 10.1039/B804573A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements