Issue 29, 2008
From the journal:

Chemical Communications

Unprecedented cationic copper(i)–iodide aggregates trapped in “click” formation of anionic-tetrazolate-based coordination polymers†

Mian Li,a   Zhen Lia  and  Dan Li*a  

* Corresponding authors

a Department of Chemistry, Shantou University, People’s Republic of China
E-mail: dli@stu.edu.cn

Abstract

A series of unprecedented cationic copper(I)–iodide aggregates, (Cu4I2)2+, (Cu6I2)4+ and (Cu10I4)6+, are trapped in the in situ formation of anionic-tetrazolate-based coordination polymers, namely [Cu2(μ3-I)(μ5-Cpta)]n (1), [Cu5(μ4-I)(μ4-Mtta)3(CN)]n (2) and [Cu5(μ6-I)(μ2-I)(μ4-Mtta)3]n (3) [Cpta = 5-(3-cyanophenyl)tetrazolate, Mtta = 5-methyltetrazolate], which exhibit structure-related green, cyan and blue luminescence, respectively.

Graphical abstract: Unprecedented cationic copper(i)–iodide aggregates trapped in “click” formation of anionic-tetrazolate-based coordination polymers

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Article information

DOI
https://doi.org/10.1039/B803636E
Article type
Communication
Submitted
03 Mar 2008
Accepted
24 Apr 2008
First published
03 Jun 2008

Chem. Commun., 2008, 3390-3392

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Unprecedented cationic copper(I)–iodide aggregates trapped in “click” formation of anionic-tetrazolate-based coordination polymers

M. Li, Z. Li and D. Li, Chem. Commun., 2008, 3390 DOI: 10.1039/B803636E

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