Facile intramolecular C(sp3)–H bond activation with PdII

Martin Bröring; Christian Kleeberg

doi:10.1039/B802185F

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Facile intramolecular C(sp³)–H bond activation with Pd^II†

Martin Bröring*^a and Christian Kleeberg^a

Author affiliations

* Corresponding authors

^a Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Straße, 35043 Marburg, Germany
E-mail: Martin.Broering@chemie.uni-marburg.de

Abstract

The treatment of bis(4-tert-butylthiazolyl)isoindoline (4-tBuBTI) with palladium acetate results in the exclusive formation of an organometallic Pd^II compound with C–H activated t-butyl group and a hemilabile S-coordinated thiazole donor in cis-position.

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Article information

DOI: https://doi.org/10.1039/B802185F
Article type: Communication
Submitted: 07 Feb 2008
Accepted: 06 Mar 2008
First published: 08 Apr 2008

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Chem. Commun., 2008, 2777-2778

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Facile intramolecular C(sp³)–H bond activation with Pd^II

M. Bröring and C. Kleeberg, Chem. Commun., 2008, 2777 DOI: 10.1039/B802185F

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