Issue 16, 2008

Preparation of silyl substituted crotylzinc reagents and their highly diastereoselectiveaddition to carbonyl compounds

Abstract

Readily prepared β-silyl substituted crotylzinc reagents undergo highly selective allylation of carbonyl compounds leading to syn-homoallylic alcohols.

Graphical abstract: Preparation of silyl substituted crotylzinc reagents and their highly diastereoselectiveaddition to carbonyl compounds

Supplementary files

Article information

Article type
Communication
Submitted
06 Feb 2008
Accepted
06 Mar 2008
First published
19 Mar 2008

Chem. Commun., 2008, 1916-1917

Preparation of silyl substituted crotylzinc reagents and their highly diastereoselectiveaddition to carbonyl compounds

M. D. Helm, P. Mayer and P. Knochel, Chem. Commun., 2008, 1916 DOI: 10.1039/B802157K

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