Issue 24, 2008
From the journal:

Chemical Communications

Nonlinear optical and ferroelectric properties of a 3-D Cd(ii) triazolate complex with a novel (63)2(610·85) topology†

Wei-Wei Zhou,ab   Jiu-Tong Chen,*a   Gang Xu,a   Ming-Sheng Wang,a   Jian-Ping Zou,a   Xi-Fa Long,a   Guo-Jian Wang,a   Guo-Cong Guo*a  and  Jin-Shun Huanga  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, P. R. China
E-mail: gcguo@fjirsm.ac.cn
Fax: 86 591 83714946

b Graduate School of Chinese Academy of Sciences, Beijing, P. R. China

Abstract

A novel 3-D (3,6)-connected topological architecture, obtained by reacting Cd(ClO4)2·6H2O with Htrtr (Htrtr = 3-(1,2,4-triazole-4-yl)-1H-1,2,4-triazole) under solvothermal conditions, presents a non-centrosymmetric polar packing arrangement, resulting in a strong second harmonic generation (SHG) response and ferroelectric property.

Graphical abstract: Nonlinear optical and ferroelectric properties of a 3-D Cd(ii) triazolate complex with a novel (63)2(610·85) topology

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Article information

DOI
https://doi.org/10.1039/B801529E
Article type
Communication
Submitted
28 Jan 2008
Accepted
05 Mar 2008
First published
10 Apr 2008

Chem. Commun., 2008, 2762-2764

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Nonlinear optical and ferroelectric properties of a 3-D Cd(II) triazolate complex with a novel (63)2(610·85) topology

W. Zhou, J. Chen, G. Xu, M. Wang, J. Zou, X. Long, G. Wang, G. Guo and J. Huang, Chem. Commun., 2008, 2762 DOI: 10.1039/B801529E

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