Issue 23, 2008
From the journal:

Chemical Communications

New catalytic route to borasiloxanes†

Bogdan Marciniec*a  and  Jędrzej Walkowiaka  

* Corresponding authors

a Department of Organometallic Chemistry, Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, Poznań, Poland
E-mail: marcinb@amu.edu.pl
Fax: +48(61)8291508
Tel: +48(61)8291366

Abstract

A new, highly selective method for effective synthesis of boryl silyl ethers (borasiloxanes) viaO-borylation of silanols with vinylboronates catalyzed by the Ru–H complexes [RuHCl(CO)(PCy3)2] and [RuHCl(CO)(PPh3)3] is described.

Graphical abstract: New catalytic route to borasiloxanes

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Article information

DOI
https://doi.org/10.1039/B801013G
Article type
Communication
Submitted
18 Jan 2008
Accepted
15 Apr 2008
First published
09 May 2008

Chem. Commun., 2008, 2695-2697

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New catalytic route to borasiloxanes

B. Marciniec and J. Walkowiak, Chem. Commun., 2008, 2695 DOI: 10.1039/B801013G

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