Issue 19, 2008
From the journal:

Chemical Communications

Control of electronic structure of a six-coordinate iron(iii) porphyrin radical by means of axial ligands

Akira Ikezaki,a   Hideyuki Tukadab  and  Mikio Nakamura*acd  

* Corresponding authors

a Department of Chemistry, Toho University, School of Medicine, Ota-ku, Tokyo 143-8540, Japan
E-mail: mnakamu@med.toho-u.ac.jp

b Graduate School of Integrated Science, Yokohama City University, Kanazawa-ku, Yokohama 236-0027, Japan

c Division of Chemistry, Toho University, Graduate School of Science, Funabashi 274-8510, Japan

d Research Center of Materials with Integrated Properties, Toho University, Funabashi, Japan

Abstract

Addition of tert-butylisocyanide (tBuNC) to a CD2Cl2 solution of the bis(perchlorato)(meso-tetramesitylporphyrinato) iron(III) cation radical leads to the formation of the corresponding bis(adduct), [Fe(TMP)(tBuNC)2]2+, whose electronic structure is in sharp contrast to that of the corresponding imidazole(HIm) complex, [Fe(TMP)(HIm)2]2+; the former adopts the S = 0 while the latter exhibits the S = 1 electronic ground state.

Graphical abstract: Control of electronic structure of a six-coordinate iron(iii) porphyrin radical by means of axial ligands

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Article information

DOI
https://doi.org/10.1039/B800674A
Article type
Communication
Submitted
14 Jan 2008
Accepted
11 Feb 2008
First published
13 Mar 2008

Chem. Commun., 2008, 2257-2259

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Control of electronic structure of a six-coordinate iron(III) porphyrin radical by means of axial ligands

A. Ikezaki, H. Tukada and M. Nakamura, Chem. Commun., 2008, 2257 DOI: 10.1039/B800674A

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