Propane reacts with O2 and H2 on gold supported TS-1 to form oxygenates with high selectivity

J. J. Bravo-Suárez; K. K. Bando; T. Akita; T. Fujitani; T. J. Fuhrer; S. T. Oyama

doi:10.1039/B800620B

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Propane reacts with O₂ and H₂ on gold supported TS-1 to form oxygenates with high selectivity†

J. J. Bravo-Suárez,^a K. K. Bando,^a T. Akita,^b T. Fujitani,^a T. J. Fuhrer^c and S. T. Oyama*^ad

Author affiliations

* Corresponding authors

^a National Institute of Advanced Industrial Science and Technology (AIST), 16-1 Onogawa, Tsukuba, Japan

^b AIST, Midorigaoka 1-8-31, Osaka, Japan

^c Chemistry and Physics, Radford University, Radford, USA

^d Chemical Engineering, Virginia Tech, Blacksburg, USA
E-mail: oyama@vt.edu
Fax: +1 540 231 5022
Tel: +1 540 231 5309

Abstract

Gold nanoparticles supported on a microporous titanosilicate (TS-1) were found to be highly selective (95%) towards the formation of acetone and isopropanol from propane, O₂, and H₂ at moderate temperatures (443 K).

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Supplementary files

Experimental section, TEM, Au L ₃ edge XANES and UV-Vis data PDF (5864K)

Article information

DOI: https://doi.org/10.1039/B800620B
Article type: Communication
Submitted: 15 Jan 2008
Accepted: 06 May 2008
First published: 13 Jun 2008

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Chem. Commun., 2008, 3272-3274

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Propane reacts with O₂ and H₂ on gold supported TS-1 to form oxygenates with high selectivity

J. J. Bravo-Suárez, K. K. Bando, T. Akita, T. Fujitani, T. J. Fuhrer and S. T. Oyama, Chem. Commun., 2008, 3272 DOI: 10.1039/B800620B

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