Issue 7, 2008
From the journal:

Chemical Communications

Direct synthesis of the 1,2,3-[C[upper bond 1 start]6H4P[horiz bar, triple dot above]P[horiz bar, triple dot above]P[upper bond 1 end]]− anion, isoelectronic with the indenyl anion [C[upper bond 1 start]6H4CH[horiz bar, triple dot above]CH[horiz bar, triple dot above]C[upper bond 1 end]H]−†

Felipe García,a   Robert J. Less,a   Vesal Naseri,a   Mary McPartlin,a   Jeremy M. Rawson,*a   Maria Sancho Tomasa  and  Dominic S. Wright*a  

* Corresponding authors

a Chemistry Department, Cambridge University, Lensfield Road, Cambridge, UK
E-mail: dsw1000@cam.ac.uk, jmr31@cam.ac.uk

Abstract

The two products obtained from the reaction of 1,2-(PH2)2C6H4 with the mixed-metal base nBuLi–Sb(NMe2)3 in the presence of 12-crown-4, [Li(12-crown-4)2]+[C6H4P3]− (1) and {[Li(12-crown-4)2]+}3[Sb11]3− (2), represent thermodynamic sinks in which P–P and Sb–Sb bonding are maximized at the expense of P–Sb bonding, providing access to the 1,2,3-[C6H4P3]− phospholide anion.

Graphical abstract: Direct synthesis of the 1,2,3-[C [[upper bond 1 start]] 6H4P [[horiz bar, triple dot above]] P [[horiz bar, triple dot above]] P [[upper bond 1 end]] ]− anion, isoelectronic with the indenyl anion [C [[upper bond 1 start]] 6H4CH [[horiz bar, triple dot above]] CH [[horiz bar, triple dot above]] C [[upper bond 1 end]] H]−

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B718425E
Article type
Communication
Submitted
28 Nov 2007
Accepted
19 Dec 2007
First published
15 Jan 2008

Chem. Commun., 2008, 859-861

Permissions

Request permissions

Direct synthesis of the 1,2,3-[C[upper bond 1 start]6H4P[horiz bar, triple dot above]P[horiz bar, triple dot above]P[upper bond 1 end]]− anion, isoelectronic with the indenyl anion [C[upper bond 1 start]6H4CH[horiz bar, triple dot above]CH[horiz bar, triple dot above]C[upper bond 1 end]H]−

F. García, R. J. Less, V. Naseri, M. McPartlin, J. M. Rawson, M. Sancho Tomas and D. S. Wright, Chem. Commun., 2008, 859 DOI: 10.1039/B718425E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements