A new hybrid framework based on a ‘superoctahedral’ [V7O6F30]14− polyanion

Thushitha Mahenthirarajah; Philip Lightfoot

doi:10.1039/B718417D

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A new hybrid framework based on a ‘superoctahedral’ [V₇O₆F₃₀]¹⁴⁻ polyanion†

Thushitha Mahenthirarajah^a and Philip Lightfoot*^a

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* Corresponding authors

^a EaStChem, School of Chemistry, University of St Andrews, St Andrews, Fife, UK
E-mail: pl@st-and.ac.uk

Abstract

Solvothermal synthesis has led to the isolation of an unusual hybrid framework solid [CH₃NH₃]₈[Cu(Py)₄]₃[V₇O₆F₃₀] in which the novel [V₇O₆F₃₀]¹⁴⁻ polyanion is linked via [Cu(py)₄]²⁺ moieties into a doubly interpenetrated cubic lattice.

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Article information

DOI: https://doi.org/10.1039/B718417D
Article type: Communication
Submitted: 28 Nov 2007
Accepted: 28 Jan 2008
First published: 15 Feb 2008

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Chem. Commun., 2008, 1401-1403

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A new hybrid framework based on a ‘superoctahedral’ [V₇O₆F₃₀]¹⁴⁻ polyanion

T. Mahenthirarajah and P. Lightfoot, Chem. Commun., 2008, 1401 DOI: 10.1039/B718417D

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Chemical Communications