Issue 13, 2008
From the journal:

Chemical Communications

Cyanide13C NMR hyperfine shifts in paramagnetic cyanide-bridged mixed-valence complexes

W. Michael Laidlaw*a  and  Robert G. Denninga  

* Corresponding authors

a Inorganic Chemistry Laboratory, South Parks Road, Oxford, UK
E-mail: michael.laidlaw@chem.ox.ac.uk, bob.denning@chem.ox.ac.uk
Fax: +44 (0)1865 272690
Tel: +44 (0)1865 272600

Abstract

Paramagnetic (hyperfine) NMR shifts in the 13C cyanide bridge and 31P resonances in a set of mixed valence complexes [(η5-C5R5)Ru(PPh3)L(13CN)Ru(NH3)5]n+ (R = H; L = PPh3, CO, NO+; R = Me; L = PPh3) are sensitive to the extent of intermetallic charge-transfer, and are strongly solvent dependent.

Graphical abstract: Cyanide 13C NMR hyperfine shifts in paramagnetic cyanide-bridged mixed-valence complexes

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Article information

DOI
https://doi.org/10.1039/B717400D
Article type
Communication
Submitted
12 Nov 2007
Accepted
18 Jan 2008
First published
08 Feb 2008

Chem. Commun., 2008, 1590-1592

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Cyanide 13C NMR hyperfine shifts in paramagnetic cyanide-bridged mixed-valence complexes

W. M. Laidlaw and R. G. Denning, Chem. Commun., 2008, 1590 DOI: 10.1039/B717400D

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