Issue 12, 2008
From the journal:

Chemical Communications

Synthesis and dynamic structure of multinuclear Rh complexes of porphyrinoids†

Jun-ichiro Setsune,*a   Masayuki Todaa  and  Takafumi Yoshidab  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Kobe University, 1-1 Rokkodai-cho, Nada-ku, 657-8501 Kobe, Japan
E-mail: setsunej@kobe-u.ac.jp
Fax: +81-78-803-5770
Tel: +81-78-803-5683

b Department of Frontier Research and Technology, Headquarters for Innovative Cooperation and Development, Kobe University

Abstract

Large porphyrinoids with three Rh(CO)2 groups at their dipyrrin units shows two-step metal transposition through the macrocycle in solution and the equilibrium between the C3v-isomer and the Cs-isomer depends on the solvent polarity.

Graphical abstract: Synthesis and dynamic structure of multinuclear Rh complexes of porphyrinoids

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Article information

DOI
https://doi.org/10.1039/B717022J
Article type
Communication
Submitted
05 Nov 2007
Accepted
23 Jan 2008
First published
19 Feb 2008

Chem. Commun., 2008, 1425-1427

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Synthesis and dynamic structure of multinuclear Rh complexes of porphyrinoids

J. Setsune, M. Toda and T. Yoshida, Chem. Commun., 2008, 1425 DOI: 10.1039/B717022J

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