Issue 11, 2008

New supramolecular isomers with 2D 44 square-grid and 3D 65·8 frameworks in a one-pot synthesis; reversible solvent uptake and intriguing luminescence properties

Abstract

Two supramolecular isomers of [Ni(4-bpd)2(NCS)2] (4-bpd = 1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene) with 2D 44 square-grid and 3D 65·8 frameworks are co-crystallized in a one-pot reaction, both of which exhibit interesting luminescence properties and reversible adsorption–desorption with respect to guest solvents.

Graphical abstract: New supramolecular isomers with 2D 44 square-grid and 3D 65·8 frameworks in a one-pot synthesis; reversible solvent uptake and intriguing luminescence properties

Supplementary files

Article information

Article type
Communication
Submitted
01 Nov 2007
Accepted
04 Jan 2008
First published
23 Jan 2008

Chem. Commun., 2008, 1299-1301

New supramolecular isomers with 2D 44 square-grid and 3D 65·8 frameworks in a one-pot synthesis; reversible solvent uptake and intriguing luminescence properties

C. Wang, W. Lin, W. Huang, M. Ko, G. Lee, M. Ho, C. Lin, C. Shih and P. Chou, Chem. Commun., 2008, 1299 DOI: 10.1039/B716953A

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