Issue 7, 2008

Enantioselective [1,2]-Stevens rearrangement of quaternary ammonium salts. A mechanistic evaluation

Abstract

Using a supramolecular asymmetric ion pairing strategy, an enantioselective [1,2]-Stevens is feasible on substrates devoid of stereogenic quaternary nitrogen atoms.

Graphical abstract: Enantioselective [1,2]-Stevens rearrangement of quaternary ammonium salts. A mechanistic evaluation

Supplementary files

Article information

Article type
Communication
Submitted
26 Oct 2007
Accepted
06 Dec 2007
First published
21 Dec 2007

Chem. Commun., 2008, 829-831

Enantioselective [1,2]-Stevens rearrangement of quaternary ammonium salts. A mechanistic evaluation

M. Gonçalves-Farbos, L. Vial and J. Lacour, Chem. Commun., 2008, 829 DOI: 10.1039/B716488B

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