Single-molecule magnet behaviour in metal–organic nanospheres generated by simple precipitation of Mn12O12 clusters

Inhar Imaz; Fernando Luis; Chiara Carbonera; Daniel Ruiz-Molina; Daniel Maspoch

doi:10.1039/B716071B

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Single-molecule magnet behaviour in metal–organic nanospheres generated by simple precipitation of Mn₁₂O₁₂ clusters†

Inhar Imaz,^a Fernando Luis,^b Chiara Carbonera,^b Daniel Ruiz-Molina^c and Daniel Maspoch*^a

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* Corresponding authors

^a Institut Català de Nanotecnologia, Campus Universitari, Catalonia, Spain
E-mail: daniel.maspoch.icn@uab.es
Fax: +34 93 581 4411
Tel: +34 93 581 4299

^b Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza, Spain

^c Centre d’Investigació en Nanociència i Nanotecnologia, Campus Universitari, Catalonia, Spain

Abstract

Metal–organic sub-50 nm spherical particles that exhibit single-molecule magnet behaviour have been fabricated by direct precipitation of Mn₁₂O₁₂ clusters in a mixture of acetonitrile and toluene.

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Supplementary files

EELS, IR, DLS and additional TEM and FE-SEM images of Mn ₁₂-based nanoparticles PDF (5898K)

Article information

DOI: https://doi.org/10.1039/B716071B
Article type: Communication
Submitted: 17 Oct 2007
Accepted: 11 Dec 2007
First published: 21 Jan 2008

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Chem. Commun., 2008, 1202-1204

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Single-molecule magnet behaviour in metal–organic nanospheres generated by simple precipitation of Mn₁₂O₁₂ clusters

I. Imaz, F. Luis, C. Carbonera, D. Ruiz-Molina and D. Maspoch, Chem. Commun., 2008, 1202 DOI: 10.1039/B716071B

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