Issue 7, 2008
From the journal:

Chemical Communications

Synthesis of a stable radical anion via the one electron reduction of a 1,1-bis-phosphinosulfide alkene derivative†

Thibault Cantat,a   Frédéric Biaso,b   Aurélien Momin,a   Louis Ricard,a   Michel Geoffroy,*b   Nicolas Mézailles*a  and  Pascal Le Floch*a  

* Corresponding authors

a Laboratoire Hétéroéléments et Coordination, Ecole Polytechnique, CNRS, Palaiseau Cédex, France
E-mail: lefloch@poly.polytechnique.fr
Fax: +33(0)1 6933 3990
Tel: +33(0)1 6933 4401

b Department of Physical Chemistry, University of Geneva, 30 quai Ernest Ansermet, 1211 Geneva 4, Switzerland
E-mail: Michel.Geoffroy@chiphy.unige.ch

Abstract

A new type of stable radical ligand featuring a 1,1-bis-phosphinosulfide alkene backbone has been prepared and characterized on the basis of X-ray diffraction, EPR and DFT studies.

Graphical abstract: Synthesis of a stable radical anion via the one electron reduction of a 1,1-bis-phosphinosulfide alkene derivative

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Article information

DOI
https://doi.org/10.1039/B715380E
Article type
Communication
Submitted
10 Oct 2007
Accepted
04 Dec 2007
First published
19 Dec 2007

Chem. Commun., 2008, 874-876

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Synthesis of a stable radical anion via the one electron reduction of a 1,1-bis-phosphinosulfide alkene derivative

T. Cantat, F. Biaso, A. Momin, L. Ricard, M. Geoffroy, N. Mézailles and P. Le Floch, Chem. Commun., 2008, 874 DOI: 10.1039/B715380E

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