Issue 13, 2008
From the journal:

Chemical Communications

Synthesis, structure and physical properties of the manganese(ii) selenide/selenolate cluster complexes [Mn32Se14(SePh)36(PnPr3)4] and [Na(benzene-15-crown-5)(C4H8O)2]2[Mn8Se(SePh)16]†

Andreas Eichhöfer,*a   Paul T. Wood,b   Raghavan N. Viswanatha  and  Richard A. Molec  

* Corresponding authors

a Institut für Nanotechnologie, Forschungszentrum Karlsruhe, Postfach 3640, Germany
E-mail: eichhoefer@int.fzk.de
Fax: +49 7247-82-6368
Tel: +49 7247-82-6371

b University Chemical Laboratory, Lensfield Rd, Cambridge, UK

c ZWE FRM-II, Lichtenbergstrasse 1, Germany

Abstract

The synthesis, molecular structures, and magnetic and optical properties of [Mn32Se14(SePh)36(PnPr3)4] and [Na(benzene-15-crown-5)(C4H8O)2]2[Mn8Se(SePh)16] have been investigated which are the first examples of manganese chalcogenide cluster complexes, despite known manganese oxo compounds, which comprise more than four manganese atoms.

Graphical abstract: Synthesis, structure and physical properties of the manganese(ii) selenide/selenolate cluster complexes [Mn32Se14(SePh)36(PnPr3)4] and [Na(benzene-15-crown-5)(C4H8O)2]2[Mn8Se(SePh)16]

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Article information

DOI
https://doi.org/10.1039/B714582A
Article type
Communication
Submitted
21 Sep 2007
Accepted
21 Jan 2008
First published
12 Feb 2008

Chem. Commun., 2008, 1596-1598

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Synthesis, structure and physical properties of the manganese(II) selenide/selenolate cluster complexes [Mn32Se14(SePh)36(PnPr3)4] and [Na(benzene-15-crown-5)(C4H8O)2]2[Mn8Se(SePh)16]

A. Eichhöfer, P. T. Wood, R. N. Viswanath and R. A. Mole, Chem. Commun., 2008, 1596 DOI: 10.1039/B714582A

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